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Synthesis of Terminally Functionalized Isotactic Poly(propylene) with a [ArN(CH2)3NAr]TiCl2 (Ar = 2,6-iPr2C6H3) – MAO Catalyst System

✍ Scribed by Shingo Tsubaki; Jizhu Jin; Tsuneji Sano; Toshiya Uozumi; Kazuo Soga


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
91 KB
Volume
202
Category
Article
ISSN
1022-1352

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Polymerization of propylene with the [Ar
✍ Jizhu Jin; Shingo Tsubaki; Toshiya Uozumi; Tsuneji Sano; Kazuo Soga 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 367 KB 👁 1 views

Polymerization of propylene was conducted at 0 -150°C with the [ArN(CH2)3NAr]TiClz (Ar = 2,6-'Pr2C6H3) complex using a mixture of ~a l k y l a l u m i n i ~ (AIR3, R = methyl, ethyl and isobutyl) and Ph3CB(C&& as cocatalyst. When AlMe3 or AlEt3 was employed, atactic polypropylene (PP) was selectivel