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Isospecific Propylene Polymerization Using the [ArN(CH2)3NAr]TiCl2/Al(iBu)3/Ph3CB(C6F5)4 Catalyst System in the Presence of Cyclohexene

โœ Scribed by Toshiya Uozumi; Shingo Tsubaki; Jizhu Jin; Tsuneji Sano; Kazuo Soga

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
89 KB
Volume
202
Category
Article
ISSN
1022-1352

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๐Ÿ“œ SIMILAR VOLUMES

Polymerization of propylene with the [Ar
Polymerization of propylene with the [ArN(CH2)3NAr]TiCl2 (Ar = 2,6-iPr2C6H3) complex using R3Al/Ph3CB(C6F5)4 (R = Me, Et, iBu) as cocatalyst
โœ Jizhu Jin; Shingo Tsubaki; Toshiya Uozumi; Tsuneji Sano; Kazuo Soga ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 367 KB

Polymerization of propylene was conducted at 0 -150ยฐC with the [ArN(CH2)3NAr]TiClz (Ar = 2,6-'Pr2C6H3) complex using a mixture of ~a l k y l a l u m i n i ~ (AIR3, R = methyl, ethyl and isobutyl) and Ph3CB(C&& as cocatalyst. When AlMe3 or AlEt3 was employed, atactic polypropylene (PP) was selectivel