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Synthesis of terminal trimethylsilyl enynes via a silylated arsonium ylide

โœ Scribed by Yanchang Shen; Qium Liao

Book ID
103223934
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
268 KB
Volume
346
Category
Article
ISSN
0022-328X

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๐Ÿ“œ SIMILAR VOLUMES

Synthesis of trimethylsily enynyl carbox
Synthesis of trimethylsily enynyl carboxylates via a silylated arsonium ylide
โœ Yanchang Shen; Yuejun Xiang ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 258 KB

Silylated t.iiFnyl curboxylic esters can be synthesized with high stereoselectivity by the reaction of 3-tri-i~ieth~~lsilyl-2-propynylide~ietriphenylarsorane, generated in sitif from the corresponding arsonium salt with 11-hirtvllithiitin and a-bromoacetic esters.