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Synthesis of terminal perfluoromethylene olefins

✍ Scribed by Kaufman, Martin H.; Braun, John D.; Shdo, Jose G.


Book ID
127079166
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
471 KB
Volume
32
Category
Article
ISSN
0022-3263

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Vicinal Diamination of Terminal Olefins
✍ Hansβ€…Rudolf Pfaendler; Alexander Klingl πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 German βš– 160 KB πŸ‘ 1 views

## Abstract The present publication describes an efficient and mild three‐step conversion of a terminal olefin **1** into the corresponding 1,2‐diamine **5**. The sequence includes: azidoiodination, substitution with NaN~3~, and catalytic hydrogenolysis. The terminal 1,2‐diamine **5** was converted