Vicinal Diamination of Terminal Olefins

✍ Scribed by Hans Rudolf Pfaendler; Alexander Klingl

• Publisher: John Wiley and Sons
• Year: 2005
• Tongue: German
• Weight: 160 KB
• Volume: 88
• Category: Article
• ISSN: 0018-019X
• DOI: 10.1002/hlca.200590119

✦ Synopsis

Abstract

The present publication describes an efficient and mild three‐step conversion of a terminal olefin 1 into the corresponding 1,2‐diamine 5. The sequence includes: azidoiodination, substitution with NaN~3~, and catalytic hydrogenolysis. The terminal 1,2‐diamine 5 was converted into its cis‐dichloroplatinum(II) complex 6.