𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of Terminal Perfluoroalkyl Enol Ethers and Epoxy Ethers

✍ Scribed by Bégué, Jean-Pierre; Bonnet-Delpon, Danièle; Andrei,


Book ID
118034686
Publisher
Taylor and Francis Group
Year
1996
Tongue
English
Weight
251 KB
Volume
26
Category
Article
ISSN
0039-7911

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Phenylthiomethylstannylation of silyl en
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Silyl enol ethers (2) react with trihutyl [(phenylthio) chloromethyl] stannane (1) in the presence of Zinc bromide to give B-phenylthiomethylstannyl ketones (3) in good yields. Silyl dienol ethers (4) mainly give products (5) due to y-attack, under these conditions. S-Stannyl Carbonyl compounds have