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Triethylborane induced perfluoroalkylation of silyl enol ethers or germyl enol ethers with perfluoroalkyl iodides

โœ Scribed by Katsukiyo Miura; Masahiko Taniguchi; Kyoko Nozaki; Koichiro Oshima; Kiitiro Utimoto


Book ID
104228367
Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
150 KB
Volume
31
Category
Article
ISSN
0040-4039

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A novel aminomethylation of silyl enol e
โœ Akira Hosomi; Susumu Iijima; Hideki Sakurai ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 224 KB

The iodotrimethylsilane-catalyzed reaction of silyl enol ethers with aminomethyl ethers in acetonitrile gives aminomethylation products of the corresponding ketones readily. The reaction can also be catalyzed by trimethylsilyl trifluoromethanesulfonate in dichloromethane. Aminomethylation of ketones