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Synthesis of Terminal and Bridging Acetonyl Complexes of Palladium(II). Crystal Structures of [{(AsPh 3 )(C 6 F 5 )Pd} 2 { μ -CH 2 C(O)CH 3 } 2 ], [(AsPh 3 )(C 6 F 5 )Pd{CH 2 C(O)CH 3 }( t -BuNC)], and [( o -C 6 H 4 CH 2 NMe 2 )Pd{ O , O ‘-CH(CO 2 Et) 2 }]

✍ Scribed by Ruiz, José; Rodríguez, Venancio; Cutillas, Natalia; Pardo, Mercedes; Pérez, José; López, Gregorio; Chaloner, Penny; Hitchcock, Peter B.

Book ID
120172308
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
175 KB
Volume
20
Category
Article
ISSN
0276-7333

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UV absorption spectra of HO2, CH3O2, C2H
UV absorption spectra of HO2, CH3O2, C2H5O2, and CH3C(O)CH2O2 radicals and mechanism of the reactions of F and Cl atoms with CH3C(O)CH3
✍ Ole J. Nielsen; Matthew S. Johnson; Timothy J. Wallington; Lene K. Christensen; 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 314 KB

## Abstract Pulse radiolysis techniques were used to measure the gas phase UV absorption spectra of the title peroxy radicals over the range 215–340 nm. By scaling to σ(CH~3~O~2~)~240 nm~ = (4.24 ± 0.27) × 10^−18^, the following absorption cross sections were determined: σ(HO~2~)~240 nm~ = 1.29 ± 0