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Synthesis of Tedanolide and 13-Deoxytedanolide. Assembly of a Common C(1)−C(11) Subtarget

✍ Scribed by Smith, Amos B.; Lodise, Stephanie A.

Book ID
127106750
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
63 KB
Volume
1
Category
Article
ISSN
1523-7060

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Progress towards the total synthesis of
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The C 1 -C 11 subunit of tedanolide was constructed using a boron-mediated syn aldol reaction as the key step to control the C 6 and C 7 stereocenters. Other features of this work include the asymmetric Sharpless dihydroxylation to incorporate the C 2 , C 3 hydroxyl groups, selective protection of t

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✍ A.F. Sviridov; M.S. Ermolenko; D.V. Yashunsky; V.S. Borodkin; N.K. Kochetkov 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 228 KB

## Erythronolide B has been synthesized starting from levoglucosan. In the preceding paper we reported the synthesis of erythronolide B (1) from levoglucosan2. The synthesis proceeded through assembly of Cl-C6 and Cg-Cl3 seg-