Total synthesis of erythronolide B. 2. Skeleton assembly in (C5C9) + (C3C4) + (C1C2) + (C11C13) sequence.

✍ Scribed by A.F. Sviridov; M.S. Ermolenko; D.V. Yashunsky; V.S. Borodkin; N.K. Kochetkov

• Publisher: Elsevier Science
• Year: 1987
• Tongue: French
• Weight: 228 KB
• Volume: 28
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)96400-1

✦ Synopsis

Erythronolide B has been synthesized

starting from levoglucosan.

In the preceding paper we reported the synthesis of erythronolide B (1) from levoglucosan2.

The synthesis proceeded through assembly of Cl-C6 and Cg-Cl3 seg-