Synthesis of syn-7,8-benzotricyclo[4.2.2.02,5]deca-3,7,9-triene. A new benzo (CH)10 hydrocarbon
โ Scribed by Ichiro Murata; Yoshikazu Sugihara; Nobuo Ueda
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- French
- Weight
- 207 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
Althoughthemultifarious nature of (CH)ioh.ydrocarbcm chemistryhas engenderedmuch recent interest in these molecules, no attention has yet been paid to the stereoelectronic control which benso fusion could exert on the various bond reorganizations characteristic 1 of the parent systems. In this prel
It was recently reported that the acetone-sensitized photoisomerisation of anti-7,8-beneotricyclo[4.2.2.0295 ]deca-3,7,9-triene (1) yields beneobasketene (2) and tetracyclic isomer (3).1 We now wish to describe our related studies on the photosensitiaed isomerization of (1) and some related compoun
is%= : The title compound which incorporates a strained bridgehead double and highly deformed cis and trans stilbene structures in bicyclo[4.2.2]decane ring system was synthesized in good yield as an air-sensitive substance. Some reactions pertinent to strain were examined.