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Synthesis of substituted cyclopropanes from vinylarenes and esters in the presence of ClnAlEt3 −nand Cp2ZrCl2as catalyst

✍ Scribed by L. O. Khafizova, P. R. Gubaidullin…


Book ID
120771888
Publisher
SP MAIK Nauka/Interperiodica
Year
2013
Tongue
English
Weight
232 KB
Volume
49
Category
Article
ISSN
1070-4280

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Kinetic model of olefin hydroalumination
✍ Lyudmila V. Parfenova; Alexandr V. Balaev; Irek M. Gubaidullin; Liya R. Abzalilo 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 213 KB

## Abstract The mechanism of α‐olefin hydroalumination by HAlBu^__i__^~2~, ClAlBu^__i__^~2~, and AlBu^__i__^~3~ in the presence of Cp~2~ZrCl~2~ catalyst has been studied. It was established that the key intermediate of the reaction is a bimetallic complex [Cp~2~ZrH~2~ · ClAlBu^__i__^~2~]~2~, which