✦ LIBER ✦

Synthesis of substances related to gibberellins part XV A partial synthesis of gibberellin C

✍ Scribed by Kenji Mori; Masanao Matsui; Yusuke Sumiki

Publisher: Elsevier Science
Year: 1964
Tongue: French
Weight: 218 KB
Volume: 5
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)89491-0

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✦ Synopsis

SINCE the total syntheaia of (f)-glbberlc1*2 and (*I-epigibberic2 acids had been accompllshed , our efforts were directed to the synthesis of gibbane compounda containing the lha-lactone bridge which is characteristic to all gibbere111ns. We now rlsh to describe a partial synthesis of gibberellln C (Ij3, a biologically active lactonic acid obtained from gibberellin Al. A diketo ester (11j4, m.p. 107-108oC, timax. (Nujol) 1736, X Part XIV, K. Mori, M. Ratsui and Y. Sumiki, Agr. Biol. Chem. (Tokyo), 28, 243 (1964). *% Biochemical Studies on "Bakanae" Funaus. Part 72. This is a part of a paper read at the 3rd I.U.P.A.C. International Spmposium on the Chemietry of Natural Products held in Kyoto, Japan, in April, 1964.

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