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Partial synthesis of tritium-labelled gibberellin-A3

✍ Scribed by M. Lischewski; G. Adam; H.-W. Liebisch; U. Pleiß

Publisher
John Wiley and Sons
Year
1982
Tongue
French
Weight
370 KB
Volume
19
Category
Article
ISSN
0022-2135

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✦ Synopsis

The epimeric gibberellin-A 7-aldehydes 1 and 2 were silylated, enolised with KH and 3labelled with -3 H20 to give after desilylation the tritium-labelled epimeric gibberellin-A ?-aldehydes 2 and 2. Subsequent acetylation, oxidation and deacetylation afforded [ 6-3H] gibberellin-A3 (6) and [ 6-3H]6-epi-gibbercllin-A provides a convenient method for the preparation of [ 6-3H] GA3 of high specific radioactivity.

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