Synthesis of Stereoisomeric Medium-Ring α,α′-Dihydroxy Cycloalkanones.
✍ Scribed by Leo A. Paquette; Ryan E. Hartung; John E. Hofferberth; Ivan Vilotijevic; Jiong Yang
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 249 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract A new strategy for implementing α‐ketol rearrangements under mild conditions is presented. The reactants are mono‐ and disilylated stereoisomers of α,α′‐ and α,β‐dihydroxycycloheptanones and ‐cyclooctanones. Compounds of this class experience ready deprotection upon treatment with tetra
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Ultrasound Promoted Synthesis of α,α'-Bis(Substituted Furfurylidene) Cycloalkanones and Chalcones. -The main advantages of the use of ultrasound are milder reaction conditions, higher yields (e.g. 85 and 94% compared to 10 and 15% for (IIIa) and (IIIb), resp.), and shorter reaction times.