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Synthesis of Stereohomogeneous Cyclopropanecarbaldehydes and Cyclopropyl Ketones by Cycloalkylation of 4-Hydroxy-1-alkenyl Carbamates.

✍ Scribed by Rainer Kalkofen; Sven Brandau; Birgit Wibbeling; Dieter Hoppe


Publisher
John Wiley and Sons
Year
2005
Weight
35 KB
Volume
36
Category
Article
ISSN
0931-7597

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## Abstract β‐Substituted alkenylcarbene complexes react with methyl ketone lithium enolates to give different carbocyclization products depending on the structure of the lithium enolate, on the metal of the carbene complex, and on the reaction media. Thus, the reactions of aryl and alkyl methyl ke