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Synthesis of Stereohomogeneous Cyclopropanecarbaldehydes and Cyclopropyl Ketones by Cycloalkylation of 4-Hydroxy-1-alkenyl Carbamates

✍ Scribed by Rainer Kalkofen; Sven Brandau; Birgit Wibbeling; Dieter Hoppe


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
124 KB
Volume
43
Category
Article
ISSN
0044-8249

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## Abstract β‐Substituted alkenylcarbene complexes react with methyl ketone lithium enolates to give different carbocyclization products depending on the structure of the lithium enolate, on the metal of the carbene complex, and on the reaction media. Thus, the reactions of aryl and alkyl methyl ke