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Synthesis of Southern (C1′—C11′) Fragment of Pamamycin-635A.

✍ Scribed by Ayako Miura; Hiromasa Kiyota; Shigefumi Kuwahara


Publisher
John Wiley and Sons
Year
2005
Weight
9 KB
Volume
36
Category
Article
ISSN
0931-7597

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Synthesis of the L-Acid (C1–C18) Fragmen
✍ Ayako Miura; Shin-ya Takigawa; Yukito Furuya; Yusuke Yokoo; Shigefumi Kuwahara; 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB

## Abstract The L‐acid (C1–C18) fragment of pamamycin‐593 and de‐__N__‐methylpamamycin‐579, strong aerial mycelium‐inducers of __Streptomyces alboniger__, was synthesized using a __cis__‐selective iodoetherification and a nucleophilic addition of a cerium acetylide to an aldehyde as the key steps.