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Synthesis of some spiro piperidino-1,2,4-triazolidines and aziridines

โœ Scribed by D. Bhaskar Reddy; A. Somasekhar Reddy; A. Padmaja


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
149 KB
Volume
10
Category
Article
ISSN
1042-7163

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โœฆ Synopsis


The oxidative cyclization of the thiosemicarbazones of 4-piperidones (2) furnished spiro piperidino-1,2,4-triazoles (3,4,5), while the pyrolysis of 5 led to spiro piperidinoaziridines (6). The new compounds were characterized by IR and 1 H NMR spectral data.


๐Ÿ“œ SIMILAR VOLUMES


ChemInform Abstract: Synthesis of Some S
โœ D. Bhaskar Reddy; A. Somasekhar Reddy; A. Padmaja ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB

## Synthesis of Some Spiro Piperidino-1,2,4-triazolidines and Aziridines. -The oxidative cyclization of thiosemicarbazones of 4-piperidones (III) (10 examples) provides a facile access to spiro(piperidine-triazoles) (IV)-(VI). Pyrolysis of spiro(piperidine-triazoles) (VI) results in a syn-eliminat