Synthesis of Some Deoxymannosyl Phosphates

✍ Scribed by Niggemann, Jutta ;Thiem, Joachim

• Publisher: John Wiley and Sons
• Year: 1992
• Tongue: English
• Weight: 480 KB
• Volume: 1992
• Category: Article
• ISSN: 0947-3440
• DOI: 10.1002/jlac.199219920192

✦ Synopsis

Abstract

3‐Deoxy‐α‐D‐arabino‐hexopyranosyl‐, 4‐deoxy‐α‐D‐lyxo‐hexopyranosyl‐ and 6‐deoxy‐α‐D‐mannopyranosyl phosphates 6, 12 and 21 were synthesized by phosphorylation of the deoxygenated glycosyl chlorides 3, 9 and 18 with silver dibenzyl phosphate and subsequent deprotection of the obtained α‐dibenzyl phosphates 4, 10 and 19.