𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of Silylborazines and Their Utilization as Precursors to Silicon-Containing Boron Nitride☆

✍ Scribed by Dileep Srivastava; Eileen N. Duesler; Robert T. Paine

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
431 KB
Volume
1998
Category
Article
ISSN
1434-1948

No coin nor oath required. For personal study only.

✦ Synopsis

The reactions of LiSi(SiMe 3 ) 3 with Cl(Me) 2 B 3 N 3 (Me) 3 , Cl 2 (Me)B 3 N 3 (Me) 3 , (ClBNMe) 3 , and (ClBNH) 3 result in the formation of molecular species (Me 3 Si) 3 Si(Me) 2 B 3 N 3 (Me) 3 , [(Me 3 Si) 3 Si] 2 (Me)B 3 N 3 (Me) 3 , [(Me 3 Si) 3 SiBNMe] 3 , and [(Me 3 -Si) 3 SiBNH] 3 . The new compounds have been characterized by spectroscopic techniques, and a single-crystal X-ray

📜 SIMILAR VOLUMES

Synthesis of polyborosilazane and its ut
Synthesis of polyborosilazane and its utilization as a precursor to boron nitride
✍ Zeng-Yong Chu; Chun-Xiang Feng; Yong-Cai Song; Xiao-Dong Li; Jia-Yu Xiao 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 125 KB 👁 2 views

## Abstract A new kind of polyborosilazane was synthesized from hexamethylcyclotrisilazane by exposure to boron trichloride. The pyrolysis of the precursor was carried out at 1250, 1600, and 1800°C in nitrogen for a dwelling time of 1 h. Characterizations were performed with Fourier transform infra

Synthesis and characterization of poly(a
Synthesis and characterization of poly(aminoborane) as a new boron nitride precursor
✍ Dong-Pyo Kim; Kyo-Tae Moon; Joong-Gon Kho; James Economy; Christel Gervais; Flor 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 198 KB 👁 2 views

During the solution reaction of NaBH 4 /(NH 4 ) 2 SO 4 in tetraglyme to form borazine, polymeric aminoborane (NH 2 BH 2 ) x has been isolated as a white powder. The powder was characterized by thermal gravimetric analysis/differential scanning calorimetry, infrared and mass spectroscopies, and powde