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Synthesis of sesquiterpene antitumor lactones. 6. cis-8a-Vinyloctahydro-3H-2-benzopyran-3,7-dione, a precursor to vernolepin

✍ Scribed by Wege, Peter M.; Clark, Robin D.; Heathcock, Clayton H.


Book ID
127017696
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
556 KB
Volume
41
Category
Article
ISSN
0022-3263

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A general approach toward Janus diones:
✍ Claude Niebel; Vladimir Lokshin; Vladimir Khodorkovsky πŸ“‚ Article πŸ“… 2008 πŸ› Elsevier Science 🌐 French βš– 228 KB

A general approach toward Janus diones involving the reaction of pyromellitic or naphthalenetetracarboxylic dianhydrides with ethyl(triphenylphosphoranylidene)acetate and subsequent rearrangement of the products is described. This approach allows avoiding the formation of poorly soluble intermediate