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Synthesis of Secondary Amines via N -(Benzoyloxy)amines and Organoboranes

โœ Scribed by Phanstiel, ; Wang, Q. X.; Powell, D. H.; Ospina, M. P.; Leeson, B. A.


Book ID
120063025
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
96 KB
Volume
64
Category
Article
ISSN
0022-3263

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Organoboranes react with nitrogen-13 labeled ammonia to produce alkylamines in moderate yield. When 13N labeled ammonia was bubbled into a tetrahydrofuran solution containing 0.5M tridecylborane, 1-[13N]aminodecane was formed in 25-30 min from the end of bombardment (EOB) in 40-60% overall yield. 1-