Synthesis of Sb(VO3)3and study of ternary systemxNH4VO3
✍ Scribed by P. Melnikov; R. V. Gonçalves; H. Wender
- Publisher
- Springer Netherlands
- Year
- 2011
- Tongue
- English
- Weight
- 464 KB
- Volume
- 105
- Category
- Article
- ISSN
- 0022-5215
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We have studied pressure-induced transitions and structural changes in isostructural strontium and barium orthovanadates, Sr 3 (VO 4 ) 2 and Ba 3 (VO 4 ) 2 , via Raman spectroscopy. The spectral changes in Ba 3 (VO 4 ) 2 can be interpreted as being due to condensation of VO 3؊ 4 units into edge-or c
Photoluminescence properties of Sr 3 (VO 4 ) 2 , Sr 2 Y 2/3Ày Eu y (VO 4 ) 2 and Sr 2 Y 2/3Àz Sm z (VO 4 ) 2 (y, z = 0, 0.1, 0.2, and 0.3) samples have been investigated. The self-activated Sr 3 (VO 4 ) 2 sample shows the activation and emission bands due to the charge transfer transition of VO 3À 4