𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of s-triazine polyetherols from bis(methoxymethyl)melamine and oxiranes

✍ Scribed by Jacek Lubczak

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
177 KB
Volume
66
Category
Article
ISSN
0021-8995

No coin nor oath required. For personal study only.

✦ Synopsis

Polyetherols containing s-triazine rings can be obtained in reactions of oxiranes with melamine derivatives. A report on the attempt to replace pentakis(methoxymethyl)melamine with bis(methoxymethyl)melamine in the synthesis is presented. The replacement simplified the procedure by eliminating the stage of transetherification with ethylene glycol. The oxirane addition was carried out without a solvent. The course of the reaction was studied and some properties of the resulting polyetherols determined.

πŸ“œ SIMILAR VOLUMES

Kinetics and mechanism of initial steps
Kinetics and mechanism of initial steps of synthesis of polyetherols from melamine and ethylene carbonate
✍ Dorota Kijowska; StanisΕ‚aw WoΕ‚owiec; Jacek Lubczak πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 114 KB πŸ‘ 1 views

## Abstract The kinetics of initial steps of formation of polyetherols in the reaction between melamine and ethylene carbonate in dimethylsulfoxide in presence of 1,4‐diazabicyclo[2.2.2]octane (DABCO) as catalyst was studied. Based upon kinetic studies performed with various concentrations of melam