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Synthesis of ruthenium complexes with planar-chiral cyclopentadienyl-pyridine or -phosphine bidentate ligands

✍ Scribed by Dodo, Noriko; Matsushima, Yuji; Uno, Mitsunari; Onitsuka, Kiyotaka; Takahashi, Shigetoshi

Book ID: 127307900
Publisher: The Royal Society of Chemistry
Year: 2000
Tongue: English
Weight: 202 KB
Volume: 1
Category: Article
ISSN: 1472-7773
DOI: 10.1039/a907145h

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## Abstract **Feel the pinch!** Planar–chiral, cationic, ruthenium–palladium complexes based on η^6^,η^1^‐coordinated ECE′ pincer ligands are synthesized as racemic mixtures by reacting ECE′–palladium complexes and [Ru(C~5~R~5~)(MeCN)~3~]^+^ arenophiles (R=H or Me). Chiral resolution of the cationi