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Diastereoselective Formation of Ruthenium-Isocyanide and -Acetylide Complexes with Planar-Chiral Cyclopentadienyl-Phosphine Ligands

✍ Scribed by Matsushima, Yuji; Onitsuka, Kiyotaka; Takahashi, Shigetoshi

Book ID: 126043265
Publisher: American Chemical Society
Year: 2005
Tongue: English
Weight: 220 KB
Volume: 24
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om0500523

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## Abstract **Feel the pinch!** Planar–chiral, cationic, ruthenium–palladium complexes based on η^6^,η^1^‐coordinated ECE′ pincer ligands are synthesized as racemic mixtures by reacting ECE′–palladium complexes and [Ru(C~5~R~5~)(MeCN)~3~]^+^ arenophiles (R=H or Me). Chiral resolution of the cationi