Synthesis of [Ru(phen) 2 dppz] 2+ -Tethered Oligo-DNA and Studies on the Metallointercalation Mode into the DNA Duplex
✍ Scribed by Ossipov, Dimitri; Pradeepkumar, P. I.; Holmer, Melcer; Chattopadhyaya, Jyoti
- Book ID
- 126198003
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 329 KB
- Volume
- 123
- Category
- Article
- ISSN
- 0002-7863
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## Abstract Two new complexes, [Ru(phen)~2~(ppd)]^2+^ (**1**) and [Ru(phen)(ppd)~2~]^2+^ (**2**) (ppd=pteridino[6,7‐__f__] [1,10]phenanthroline‐11,13(10__H__,12__H__)‐dione, phen=1,10‐phenanthroline) were synthesized and characterized by ES‐MS, ^1^H‐NMR spectroscopy, and elemental analysis. The int
## Abstract A novel ligand 3‐(1__H__‐imidazo[4,5‐__f__][1,10]phenanthrolin‐2‐yl)‐4__H__‐1‐benzopyran‐4‐one (ipbp) and its ruthenium(II) complexes [Ru(bpy)~2~(ipbp)]^2+^ (**1**) and [Ru(ipbp)(phen)~2~]^2+^ (**2**) (bpy=2,2′‐bipyridine, phen=1,10‐phenanthroline) were synthesized and characterized by