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Synthesis of racemic .alpha.-trans- and .beta.-trans-bergamotene

โœ Scribed by Corey, E. J.; Cane, David E.; Libit, Lawrence


Book ID
120476617
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
893 KB
Volume
93
Category
Article
ISSN
0002-7863

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Simple synthesis of (ยฑ)-ฮฒ-trans-bergamot
โœ E.J. Corey; Manoj C. Desai ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 288 KB

## Bergamotene ( 2) has been synthesized in five steps from geranylacetone using intramolecular ketene-olefin cycloaddition as a key step. We have recently completed a synthesis of retigeranic acid (L )l in which the pentacyclic system was generated by intramolecular cycloaddition of the ketene2

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