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Synthesis of rac-2′-(trimethylsilyl)isovaline: A novel silicon-containing α,α-dialkylated α-amino acid

✍ Scribed by Steffen Falgner; Ginka Buchner; Reinhold Tacke

Book ID
118475753
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
236 KB
Volume
695
Category
Article
ISSN
0022-328X

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A convenient synthesis of tetrazole, pre
A convenient synthesis of tetrazole, precursors of α-dialkylated α-amino acids, by reaction of trimethylsilyl azide with α-dialkylated β-ketoesters
✍ Henri-Jean Cristau; Xavier Marat; Jean-Pierre Vors; Jean-Luc Pirat 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 132 KB

The Schmidt rearrangement using trimethylsilyl azide with various a-dialkylated b-keto esters affords a convenient synthesis of tetrazole, precursors of a-dialkylated a-amino acids.