๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Synthesis of pyropheophytin-anthraquinone linked molecules as models for the study of photoinduced electron transfer

โœ Scribed by Andrei Y. Tauber; Risto K. Kostiainen; Paavo H. Hynninen

Book ID
104203081
Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
733 KB
Volume
50
Category
Article
ISSN
0040-4020

No coin nor oath required. For personal study only.

โœฆ Synopsis

Abstractz me fmt synthesis of pyropheophytin-anthraquinone compounds with the quinone covalenUy linked to the P4 allylic position of the phytyl chain is described. The results of preliminary conformational studies are reported for the two P4 steaeoisomers obtained. These results suggest differences in the orientation of the anthraquinonyl-phytyI moiety relative to the phorbin macrocycle In the isomers.

๐Ÿ“œ SIMILAR VOLUMES

Novel Model Compounds for Photoinduced E
Novel Model Compounds for Photoinduced Electron Transfer: Structures of the Folded Conformers of Zinc(II)โ€“Pyropheophytinโ€“ Anthraquinone Dyads
โœ Juho Helaja; Andrei Y. Tauber; Ilkka Kilpelรคinen; Paavo H. Hynninen ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 477 KB

The solution structures of the P4-epimers of Zn(II)-pyropheophytin-anthraquinone dyads (ZnPQ1 and ZnPQ2) were determined using two-dimensional NMR spectroscopy and molecular modeling. The mutual orientation of the anthraquinone and Zn-pyropheophytin rings was found to be di โ€ erent in the two P4-epim

Selectively metalated doubly cofacial po
Selectively metalated doubly cofacial porphyrin trimers. New models for the study of photoinduced intramolecular electron transfer.
โœ Michael R. Wasielewski; Mark P. Niemczyk; Walter A. Svec ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 243 KB

The preparation of a doubly cofacial porphyrin trimer consisting of a Zn mesoporphyrin -Zn mesoporphyrin mesoporphyrin stack is described. The optical absorp,tion and fluorescence properties of the molecule as a function of solvent are also reported.