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Models for photoinduced electron transfer: Synthesis and optical properties of quinone substituted, phenyl linked porphyrin dimers and trimers

✍ Scribed by VincentL. Capuano; MartinR. Johnson; JonathanL. Sessler

Publisher: Elsevier Science
Year: 1989
Tongue: English
Weight: 80 KB
Volume: 36
Category: Article
ISSN: 0162-0134
DOI: 10.1016/0162-0134(89)84210-2

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The quinone-linked porphyrin dimer 2 was prepared by the coupling of dipyrrolic intermediates. Compound 2, as a dilute solution in toluene, shows no detectable fluorescence when irradiated at 407 nm. Complex photosynthetic models containing two or more porphyrins with covalently attached acceptors