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Synthesis of pyridinium salts by the reaction of α, β-unsaturated ketones, primary amines, and compounds with labile hydrogen atoms

✍ Scribed by V. A. Kaminskii; G. Ya. Shevchuk; M. N. Tilichenko


Book ID
112359513
Publisher
Springer US
Year
1985
Tongue
English
Weight
436 KB
Volume
21
Category
Article
ISSN
0009-3122

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One-step synthesis of α,β-unsaturated ke
✍ Jiro Tsuji; Ichiro Minami; Isao Shimizu 📂 Article 📅 1983 🏛 Elsevier Science 🌐 French ⚖ 115 KB

Enol acetates derived from saturated ketones are converted to a,&unsaturated ketones by heating with ally1 methyl carbonate in MeCN by bimetallic catalysis of palladiumphosphine complex and tin methoxide. Conversion of saturated ketones to corresponding a,&unsaturated ketones is an important synthet