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Synthesis of chiral organophosphorus compounds by the reaction of dibenzylphosphine oxide with α,β-unsaturated ketones of the terpene series

✍ Scribed by V.D. Kolesnik; A.V. Tkachev

Book ID
111537669
Publisher
Springer
Year
2003
Tongue
English
Weight
453 KB
Volume
52
Category
Article
ISSN
1573-9171

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✍ Asaf Alimardanov; Ei-ichi Negishi 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 262 KB

Treatment of c~-silyl-cc,[~-unsaturated enones, readily preparable as regio-and stereodefined compounds in high yields, with either 2 equiv, oflCl or one equiv, each oflC1 and A1C13 provides the corresponding cc-iodo-a,[3unsaturated enones in high yields.