✦ LIBER ✦

Synthesis of poly[isobutyl (2S,3R)-3-benzyloxyaspartate]

✍ Scribed by María de Gracia García-Martín; María Violante de Paz; Juan Antonio Galbis

Publisher: John Wiley and Sons
Year: 1997
Tongue: English
Weight: 466 KB
Volume: 198
Category: Article
ISSN: 1022-1352
DOI: 10.1002/macp.1997.021980116

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✦ Synopsis

Abstract

A chiral poly(3‐substituted isobutyl D‐aspartate) 12 was synthesized by polymerization of the chiral β‐lactam 11 derived from D‐glyceraldehyde. The new polyamide was characterized by elemental analyses, and infrared, ^1^H‐ and ^13^C nuclear magnetic resonance spectroscopies. The molecular weight was estimated as 543 000 and 230 000 on the basis of viscosimetric measurements and gel‐permeation chromatography, respectively. Polyamide 12 is soluble in a variety of organic solvents including chloroform.

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