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Synthesis of Polyhydroxycyclohexanes and Relatives from (−)-Quinic Acid †

✍ Scribed by González, Concepción; Carballido, Montserrat; Castedo, Luis

Book ID
127032211
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
148 KB
Volume
68
Category
Article
ISSN
0022-3263

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The synthesis of a large variety of enantiomerically pure substituted reactive cyclopentenes **16, 23, 24** and **28** have been synthesized from the readily available (−)‐quinic acid **1**. The straightforward strategy involves a high‐yielding intramolecular aldolization‐dehydration of acyclic 1,6‐