𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of carba-sugars from (−)-quinic acid

✍ Scribed by Montserrat Carballido; Luis Castedo; Concepción González

Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
121 KB
Volume
42
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

acid (4b) are reported. The syntheses exploit the diastereoselective oxidation of the 5,6-double bond of the quinic acid-derived lactone 2 with osmium tetroxide.

📜 SIMILAR VOLUMES

Synthesis of Enantiomerically Pure Subst
Synthesis of Enantiomerically Pure Substituted Cyclopentenes from (−)-Quinic Acid
✍ Jean-Claude Barrière; Jeanine Cléophax; Stephan D. Géro; Marc Vuilhorgne 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 German ⚖ 698 KB

The synthesis of a large variety of enantiomerically pure substituted reactive cyclopentenes **16, 23, 24** and **28** have been synthesized from the readily available (−)‐quinic acid **1**. The straightforward strategy involves a high‐yielding intramolecular aldolization‐dehydration of acyclic 1,6‐