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Synthesis of Polycyclic Structures by the Diels−Alder Reaction of Inner-Outer-Ring 1,3-Bis(trimethylsilyloxy)dienes

✍ Scribed by Pérez Sestelo, José; Real, María del Mar; Sarandeses, Luis A.


Book ID
126296982
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
113 KB
Volume
66
Category
Article
ISSN
0022-3263

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Inner–outer ring 1,3-bis(trimethylsilylo
✍ Ma̱ del Mar Real; José Pérez Sestelo; Luis A. Sarandeses 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 110 KB

Functionalized benzo[c] phenanthrenes ([4]helicenes) and [5]helicenes were synthesised in five steps from tetrahydronaphthalenone and tetrahydrophenanthrenone compounds using a novel synthetic approach based on a Diels-Alder reaction between inner-outer ring 1,3-bis(trimethylsilyloxy)-1,3-dienes an