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Synthesis of Poly(alcohol)s by Hydroboration/Oxidation of Poly(methylallene) Prepared by π-Allylnickel-Catalyzed Living Coordination Polymerization

✍ Scribed by Tomohiro Kino; Ikuyoshi Tomita


Book ID
106000937
Publisher
Springer
Year
2005
Tongue
English
Weight
259 KB
Volume
55
Category
Article
ISSN
0170-0839

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## Abstract Living radical polymerization of lauryl acrylate was achieved by SET/DTLRP in water catalyzed by sodium dithionite. The work describes the synthesis of a highly hydrophobic and polar monomer in aqueous medium. The plots of $\overline M \_{\rm n}$ versus conversion and ln[M]~0~/[M] versu