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Synthesis of phenols from metal-carbynes and diynes

✍ Scribed by Timothy M. Sivavec; Thomas J. Katz

No coin nor oath required. For personal study only.

✦ Synopsis

Metal-carbynes RCzM(C0)4Rr with diacetylenes give specific phenols in good yield. The reactions take only a few minutes at or below room temperature.

Metal-carbynes, unlike metal-carbenes, 1 have rarely been considered reagents for organic

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