𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of Phakellistatin 13 and Oxidation to Phakellistatin 3 and Isophakellistatin 3

✍ Scribed by Greenman, Kevin L.; Hach, Dana M.; Van Vranken, David L.


Book ID
120623560
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
102 KB
Volume
6
Category
Article
ISSN
1523-7060

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Synthesis of [3″-3H]taxol and [13-3H]tax
✍ George F. Taylor; Stephen S. Thornton; C. Ray Tallent; John A. Kepler 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 French ⚖ 677 KB

## Abstract 7‐Trietylsilylbaccatin III (11) was coupled with cis‐1‐benzoyl‐3‐triethylsiloxy‐4‐(3′‐bromophenyl)azetidin‐2‐one. Hydrolysis of the silyl groups gave 3″‐bromotaxol which was reduced with tritium gas to give[3″‐^3^H]taxol with specific activity of 19.3 Ci mmol. Reduction of 7‐triethylsil