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Synthesis of pentavalent imidovanadium complexes and their catalyses for the polymerization of ethylene and propylene

✍ Scribed by Yoshinori Sato; Yuushou Nakayama; Hajime Yasuda

Book ID
101587649
Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
105 KB
Volume
97
Category
Article
ISSN
0021-8995

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✍ Jiling Huang; Zuofeng Feng; Hong Wang; Yanlong Qian; Junquan Sun; Yongjin Xu; We πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 English βš– 134 KB

Five new hetero-bimetallic metallocene complexes were synthesized by the reaction of RCpTiCl 3 and a Si-bridged zirconocene complex in refluxing toluene. They were all well characterized. These complexes activated with methylaluminoxane (MAO) are highly active catalysts for the polymerization of eth