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Synthesis of oxazolidin-2-ones using carbonate ion on a polymeric support
β Scribed by Giuliana Cardillo; Mario Orena; Sergio Sandri; Claudia Tomasini
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- French
- Weight
- 360 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0040-4020
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π SIMILAR VOLUMES
A simple and efficient method has been developed for the synthesis of 2-aminothiazoles from a-bromo ketones in one-pot using a supported reagents system, KSCN/SiO 2 -RNH 3 OAc/Al 2 O 3 , in which a-bromo ketone reacts first with KSCN/SiO 2 and the product, a-thiocyano ketone, reacts with RNH 3 OAc/A
N,N-dimethylacrylamide with most solvents (e. g..water, alcohols, benzene, light petroleum) a bead polymer ( 7) is only accessible in this way. (7) To a suspension of polymer (6) (12.1 g) in acetone (350ml) and glacial acetic acid (600mg) in a glass autoclave cooled to 0Β°C is added anhydrous dimethy
An improved electrochemical synthesis of chiral oxazolidin-2-ones from chiral 1,2-amino alcohols is obtained by direct electrolysis of solutions of MeCN-TEAP containing the amino alcohol, with subsequent CO 2 bubbling and addition of TsCl. This synthesis avoids any addition of bases or probases and