ChemInform Abstract: Manganese Catalyzed
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N. KOMIYA; S. NOJI; S.-I. MURAHASHI
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Article
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2010
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John Wiley and Sons
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Manganese Catalyzed Asymmetric Oxidation of Alkanes to Optically Active Ketones Bearing Asymmetric Center at the ฮฑ-Position. -Symmetrical alkanes (II) and (IV) are oxidized with iodosobenzene/4phenylpyridine-N-oxide in the presence of catalytic chiral (salen)Mn(III) complexes (I) providing optically