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Synthesis of Optically Active Pyridines with a Chiral Center at the Next Position to the Ring

โœ Scribed by Jun'ichi Uenishi; Sachiko Aburatani


Publisher
John Wiley and Sons
Year
2007
Weight
11 KB
Volume
38
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Manganese Catalyzed
โœ N. KOMIYA; S. NOJI; S.-I. MURAHASHI ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 32 KB ๐Ÿ‘ 1 views

Manganese Catalyzed Asymmetric Oxidation of Alkanes to Optically Active Ketones Bearing Asymmetric Center at the ฮฑ-Position. -Symmetrical alkanes (II) and (IV) are oxidized with iodosobenzene/4phenylpyridine-N-oxide in the presence of catalytic chiral (salen)Mn(III) complexes (I) providing optically