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Synthesis of Oligothiophene-Layered Polymers

✍ Scribed by Yasuhiro Morisaki; Jonas Alves Fernandes; Yoshiki Chujo

Book ID
102493658
Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
266 KB
Volume
30
Category
Article
ISSN
1022-1336

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✦ Synopsis

Abstract

Polymers with layered π‐electron systems comprising bithiophenes and quaterthiophenes based on a xanthene skeleton have been synthesized by an iron‐catalyzed oxidative coupling reaction. The polymers are well soluble in common organic solvents, and polymer thin films are readily obtained by a spin‐coating or casting technique. The synthesized polymers exhibit good thermal stability, and their 10% weight loss temperatures are approximately 400 °C. These behaviors of the polymers suggest that they can be used as opto‐electronic devices such as hole‐transporting materials.

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