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Synthesis and Properties of Oligophenylene-Layered Polymers

✍ Scribed by Yasuhiro Morisaki; Hiroaki Imoto; Junpei Miyake; Yoshiki Chujo

Book ID
102492680
Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
323 KB
Volume
30
Category
Article
ISSN
1022-1336

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✦ Synopsis

Abstract

We report syntheses of phenylene‐, biphenylene‐, and terphenylene‐layered polymers with a xanthene scaffold by the modified Suzuki‐Miyaura coupling reaction. Their optical properties were studied in detail. The polymer end‐capped by nitrobenzene units, which act as fluorescence quenchers, exhibited the photo‐excited energy transfer from the layered oligophenylenes to the terminal units.

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