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Synthesis of oligosaccharide substrates for N-linked glycoprotein processing enzymes

✍ Scribed by Rakesh K. Jain; Xiao-Gao Liu; Subba Rao Oruganti; E.V. Chandrasekaran; Khushi L. Matta

Book ID: 102990523
Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 641 KB
Volume: 271
Category: Article
ISSN: 0008-6215
DOI: 10.1016/0008-6215(95)00073-3

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✦ Synopsis

The stereoselective syntheses of one pentasaccharide and one tetrasaccharide containing the Glc-a-(1 ~ 3)-Man-a moiety as their terminal unit, as well as one tetrasaccharide and one trisaccharide containing the Man-a-(1 ---, 2)-Man-a terminal unit were accomplished through the utilization of two key glycosyl donors, namely, 4-pentenyl 3-O-acetyl-2,4,6-tri-O-benzyl-a-Dmannopyranoside and ethyl 2- O-acetyl-3,4,6-tri-O-benzyl-l-thio-a-D-mannopyranoside.

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