## Abstract The random copolymerization of the __N__‐carboxyhydrides of γ‐benzyl‐L‐glutamate and L‐valine using triethylamine as the initiator in low dielectric media reults in high‐molecular‐weight copolymers at low convenrson. This behavior makes it possible to apply the monomer reactivity ration
Synthesis of Nɛ-protected-L-lysine and γ-benzyl-L-glutamate N-carboxyanhydrides (NCA) by carbamoylation and nitrosation
✍ Scribed by W. Vayaboury; O. Giani; H. Collet; A. Commeyras; F. Schué
- Book ID
- 106221060
- Publisher
- Springer
- Year
- 2004
- Tongue
- English
- Weight
- 166 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0939-4451
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📜 SIMILAR VOLUMES
The yethyl-bglutamate NCA polymerization initiated by di-n-butyl and di-isopropyl amine was studied. The experimental kinetic curves show an autocatalytic portion with 2530% conversion, followed by a pseudo first-order region which extends up to at least 8590%. In this linear region, the reaction or
The solvent-and pH-induced conformational changes are examined in order to investigate the influence of benzy 1 group. Polymer was prepared via N'-benzyloxycarbonyl, N'-benzyl-Nu-carboxy-clysine anhydride. The resulting poly(iV'-benzyloxycarbonyl, N'-benzyl-clysine) was obtained in a high yield and