## Abstract Differential enthalpic analysis of a series of 3′,5′‐cyclic nucleotides indicates that homolytic cleavage of the six‐membered phosphate ring occurs either immediately prior to or concurrent with decomposition of the crystal lattice. Homolysis is followed by a rapid polymerization to yie
Synthesis of Nucleoside 3′,5′-Cyclic Boranophosphorothioate, a New Type of Cyclic Nucleotide.
✍ Scribed by Ping Li; Barbara Ramsay Shaw
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 95 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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the mother liquors produce further 16 %. After being washed with cold ethanol and ether, the crystals are analytically pure. The proton magnetic resonance spectrum 141 gave the following data (numbers indicate p.p.m with tetramethylsilane as standard) : Si(CH& Si-CHz-Si S-CHI-C C-CH2-0 0.6 3.0 3.8 4