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Synthesis of Novel Well-Defined Poly(vinyl acetate)- b -poly(acrylonitrile) and Derivatized Water-Soluble Poly(vinyl alcohol)- b -poly(acrylic acid) Block Copolymers by Cobalt-Mediated Radical Polymerization

✍ Scribed by Debuigne, Antoine; Warnant, Jérôme; Jérôme, Robert; Voets, Ilja; de Keizer, Arie; Cohen Stuart, Martien A.; Detrembleur, Christophe


Book ID
121351319
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
186 KB
Volume
41
Category
Article
ISSN
0024-9297

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## Abstract A novel block copolymer, poly(ε‐caprolactone)‐__b__‐poly(4‐vinyl pyridine), was synthesized with a bifunctional initiator strategy. Poly(ε‐caprolactone) prepolymer with a 2,2,6,6‐tetramethylpiperidinyloxy (TEMPO) end group (PCL~T~) was first obtained by coordination polymerization, whic